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Turner 2004

Watson-Crick Helices

(Example 2)

 

 

example structure        

∆G°37 = ∆G°37 intermolecular initiation + ∆G°37(GC followed by CG) + ∆G°37(CG followed by AU) + ∆G°37(AU followed by CG) + ∆G°37(CG followed by GC)

 

∆G°37 = 4.09 kcal/mol – 3.42 kcal/mol – 2.11 kcal/mol – 2.24 kcal/mol – 2.36 kcal/mol

 

∆G°37 = –6.04 kcal/mol

 

∆H°= ∆H°intermolecular initiation + ∆H°(GC followed by CG) + ∆H°(CG followed by AU) + ∆H°(AU followed by CG) + ∆H°(CG followed by GC)

 

∆H°= 3.61 kcal/mol – 14.88 kcal/mol – 10.44 kcal/mol – 11.40 kcal/mol – 10.64 kcal/mol

 

∆H°= –43.75 kcal/mol